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Thermaldecomposition kinetics of some aromatic azomonoethers |
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| Authors: | A. Rotaru Anca Moanta I. Sălăgeanu P. Budrugeac E. Segal |
| Affiliation: | (1) Laser Department, INFLPR-National Institute for Laser, Plasma and Radiation Physics, Bvd. Atomistilor, Nr. 409, Magurele, PO Box MG-16, RO-077125 Bucharest, Romania;(2) Faculty of Chemistry, University of Craiova, Calea Bucuresti Str., Nr. 107 I, Craiova, Romania;(3) School of Chemistry, University of St Andrews, North Haugh, KY16 9ST St Andrews, Fife, UK;(4) Faculty of Physics, University of Craiova, A.I. Cuza Str. Nr. 13, Craiova, Romania;(5) Faculty of Chemistry, University of Bucharest, Bvd. Regina Elisabeta Nr. 4-12, Bucharest, Romania |
| Abstract: | The non-isothermal kinetic parameters corresponding to the decomposition of 4-[(4-chlorobenzyl)oxy]-4’-nitro-azobenzene were evaluated. The kinetic analysis was performed by means of different multi-heating rates methods: isoconversional (‘model-free’) methods (Flynn–Wall–Ozawa) and invariant kinetic parameters method (IKP) associated with the criterion of the independence of activation parameters on the heating rate. The values of the obtained non-isothermal kinetic parameters are in satisfactory agreement. |
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