| Synthesis and Characterization of a Novel 3D Coordination Polymer Based on Cu（II） Cations and Mellitic Acid |
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| 作者姓名： | YANG E ;QIN Ye-Yan ;CAO Xin-Yi ;LIN Qi-Pu ;YIN Pei-Xiu ;YAO Yuan-Gen |
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| 作者单位： | [1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China [2]College of Chemistry ＆ Materials Science, Fujian Normal University, Fuzhou 350007, China |
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| 基金项目： | This work was supported by the State Key Basic Research and Development Plan of China （001CB108906）; the Knowledge Innovation Program of the Chinese Academy of Sciences; the NSF （E0620005）; the Major Special Foundation of Fujian Province （2005HZ1027, 2005HZO 1-1 ） and the Natural SCience Foundation of Fujian Province （2006F3042） |
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| 摘 要： | A new mellitate complex Cu3（μ2-mellitate）（μ2-H2O）（H2O）2·H2O]n 1 has been synthesized by the reaction of mellitic acid and Cu（CH3COO）2·H2O in the presence of base. Crystallographic data for 1： C12H8O16Cu3, Mr = 598.80, orthorhombic, Pbcn, a = 8.4378（6）, b = 10.0396（7）, c = 17.6799（12）A, V = 1497.70（18）A^3, Z = 4, De = 2.656 g/cm^3, μ = 4.327 mm^-1, F（000） = 1180, R = 0.0431 and wR = 0.0964 for 1075 observed reflections （I 〉 2σ（I））. X-ray crystal structural analysis revealed that the mellitate anions behave as the bridging ligands and link eight copper atoms repeatedly to form a novel three-dimensional metal-organic coordination polymer with two different rhombic tunnels in the solid-state structure.
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| 关 键 词： | 铜 合成 结构表征 金属有机共聚体 |
Synthesis and Characterization of a Novel 3D Coordination Polymer Based on Cu(II) Cations and Mellitic Acid |
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| YANG E,;QIN Ye-Yan,;CAO Xin-Yi,;LIN Qi-Pu,;YIN Pei-Xiu,;YAO Yuan-Gen.Synthesis and Characterization of a Novel 3D Coordination Polymer Based on Cu(II) Cations and Mellitic Acid[J].Chinese Journal of Structural Chemistry,2008,27(8):985-989. |
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| Authors: | YANG E QIN Ye-Yan CAO Xin-Yi LIN Qi-Pu YIN Pei-Xiu YAO Yuan-Gen |
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| Abstract: | A new mellitate complex Cu3(μ2-mellitate)(μ2-H2O)(H2O)2·H2O]n 1 has been synthesi-zed by the reaction of mellitic acid and Cu(CH3COO)2·H2O in the presence of base. Crystallogra-phic data for 1: C12H8O16Cu3, Mr = 598.80, orthorhombic, Pbcn, a = 8.4378(6), b = 10.0396(7), c = 17.6799(12) , V = 1497.70(18) 3, Z = 4, Dc = 2.656 g/cm3, μ = 4.327 mm–1, F(000) = 1180, R = 0.0431 and wR = 0.0964 for 1075 observed reflections (I > 2σ(I)). X-ray crystal structural analysis revealed that the mellitate anions behave as the bridging ligands and link eight copper atoms repeatedly to form a novel three-dimensional metal-organic coordination polymer with two different rhombic tunnels in the solid-state structure. |
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| Keywords: | mellitate copper metal-organic coordination polymer rhombic tunnel |
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