Chromatographic behaviour of metal ions on tin(IV) and titanium(IV) antimonate papers |
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| Authors: | R. P. S. Rajput N. S. Seth |
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| Affiliation: | (1) Chemistry Department, Bareilly College, Bareilly U.P., India |
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| Abstract: | Summary The chromatographic behaviour of 49 metal ions has been studied on papers impregnated with Sn(IV) and Ti(IV) antimonates in aqueous HNO3 and mixed solvent systems containing dimethyl sulphoxide. Numerous separations have been achieved and the Alberti equation, for Sn(IV) and Ti(IV) antimonate papers, in the modified form: –nloga K+=RM + constant (a K+=activity of K+), has been verified. The effect of the concentration of impregnating reagents on these papers has been determined and compared with other papers. The effect of pH on Rf, Ri, log Rf and RM values of metal ions has also been examined in aqueous systems. |
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| Keywords: | Ion-exchange Paper chromatography Sn(IV) antimonate paper Ti(IV) antimonate paper |
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