Nachweis und Anwendung von Gaskomplexen beim Chemischen Transport |
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| Authors: | Harald Schfer Michael Binnewies Walter Domke Jutta Karbinski |
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| Institution: | Harald Schäfer,Michael Binnewies,Walter Domke,Jutta Karbinski |
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| Abstract: | Evidence and Applications of Gaseous Complexes during the Chemical Transport By means of the chemical transport method the formation of gaseous complex compounds has been observed. Using Al2Cl6 as a transport agent, the chlorides FeCl2, CoCl2, NiCl2, CuCl2, PdCl2, PtCl2, MoCl3, YCl3, LaCl3, ThCl4 and UCl4 are transported within a temperature gradient. Similary are transported by means of Ga2Cl6 the chlorides CoCl2 and NiCl2, by means of Fe2Cl6 the chlorides FeCl2, CuCl2 and YCl3, by means of NbCl5 the chlorides NaCl and CrCl3. Examples concerning the practical application of gaseous complexes are refered. |
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