Transformations of epoxide derived from nopol over askanite-bentonite clay |
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Authors: | I V Il’ina K P Volcho D V Korchagina N F Salakhutdinov V A Barkhash |
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Institution: | (1) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent eva 9, 630090 Novosibirsk, Russia |
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Abstract: | Transformations of epoxide derived from nopol in the presence of natural askanite-bentonite clay were studied. The major products of the isomerization in the cold are diols possessing a p-menthane skeleton, which are readily converted into bicyclic ethers when the reaction is carried out at room temperature.Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 10, 2004, pp. 1483–1487.Original Russian Text Copyright © 2004 by Il ina, Volcho, Korchagina, Salakhutdinov, Barkhash. |
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