Substituted 1,4-dicyclohexyl-butan-1-ols A new class of liquid-crystalline compounds |
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Authors: | K Müller U Anker H-J Deutscher H Kresse |
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Institution: | 1. P?dagogische Hochschule , Fachbereich Chemie Hoher Weg 7, O-4020, Halle/Saale, Germany;2. P?dagogische Hochschule , Fachbereich Chemie Hoher Weg 7, O-4020, Halle/Saale, Germany;3. Veszpremer Strasse 15, 4070, Halle/Saale, Germany;4. Martin-Luther-Universit?t Halle/Wittenberg, Institut für Physikalische Chemie , Mühlpforte 1, O-4050, Halle/Saale, Germany |
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Abstract: | Abstract 1,4-dicyclohexyl-butan-1-ols with a lateral hydroxyl group in the middle part of the molecule exhibit higher clearing temperatures than those of the respective compounds whithout this lateral group. A smectic B-like texture and a low temperature additional phase X were found by microscopic and calorimetric investigations. A further unexpected result was the strong increase of the dielectric constant at the SB/X transition. These preliminary results are explained in terms of hydrogen bridges. |
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