| 钯催化[4+2]环加成反应的研究进展 |
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| 引用本文： | 段泽斌,龙玉华,杨定乔. 钯催化[4+2]环加成反应的研究进展[J]. 有机化学, 2010, 30(3): 368-380 |
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| 作者姓名： | 段泽斌 龙玉华 杨定乔 |
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| 作者单位： | 华南师范大学化学与环境学院,广州,510006 |
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| 基金项目： | 国家级.国家自然科学基金 |
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| 摘 要： | 综述了近年来钯催化[4+2]环加成反应的研究进展.重点讨论了钯催化[4+2]环加成反应的影响因素,如二烯体和亲二烯体、催化剂用量、配体、溶剂、反离子、温度及反应时间
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| 关 键 词： | 钯催化 Diels-Alder 反应 [4＋2]环加成 反应机理 研究进展 |
| 收稿时间： | 2009-04-27 |
| 修稿时间： | 2009-08-21 |
Progress in Palladium-Catalyzed Diels-Alder [4+2] Cycloaddition Reaction |
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| Duan Zebin,Long Yuhua,Yang Dingqiao. Progress in Palladium-Catalyzed Diels-Alder [4+2] Cycloaddition Reaction[J]. Chinese Journal of Organic Chemistry, 2010, 30(3): 368-380 |
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| Authors: | Duan Zebin Long Yuhua Yang Dingqiao |
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| Affiliation: | (School of Chemistry and Environment, South China Normal University, Guangzhou 510006) |
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| Abstract: | The recent progress in palladium-catalyzed [4+2] cycloaddition reaction is reviewed. The main focuses are the influences of some factors, such as the substrates of diene and dienophile, the amount of catalysts, chiral ligands, solvents, counter ions, temperature and reaction time, on the Pal-catalyzed Di-els-Alder [4-t-2] reaction. Moreover, the stereoselectivity and possible mechanisms of the [4+2] cycloaddi-tion are discussed. |
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| Keywords: | palladium-catalyzed Diels-Alder reaction [4+2] cycloaddition reaction mechanism research progress |
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