| Synthesis and Crystal Structure of Pyridine－2－thiolato－Molybdenum Complex［Et_4N］［Mo（CO_4）（pyS）］ |
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| 作者姓名： | Yu Pei-Hua Huang Liang-Ren Zhuang Bo-Tao |
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| 作者单位： | Fijian Institute of Research on the Structure of Matter，Chinese Academy of Sciences;State Key Laboratory of Structural Chemistry.Fuzhou，Fujian 350002，China |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＰｙｒｉｄｉｎｅ－２－ｔｈｉｏｌａｔｏ－ＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘ［Ｅｔ_４Ｎ］［Ｍｏ（ＣＯ_４）（ｐｙＳ）］ＹｕＰｅｉ－Ｈｕａ；ＨｕａｎｇＬｉａｎｇ－Ｒｅｎ；ＺｈｕａｎｇＢｏ－Ｔａｏ...
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Synthesis and Crystal Structure of Pyridine-2-thiolato-Molybdenum Complex[Et_4N][Mo (CO_4)(pyS)] |
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| Yu Pei-Hua,Huang Liang-Ren,Zhuang Bo-Tao.Synthesis and Crystal Structure of Pyridine-2-thiolato-Molybdenum Complex[Et_4N][Mo (CO_4)(pyS)][J].Chinese Journal of Structural Chemistry,1994(5). |
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| Authors: | Yu Pei-Hua Huang Liang-Ren Zhuang Bo-Tao |
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| Abstract: | C(17)H(24)MoN2O4S,Mr.=448.40,Orthorhombic,P212121 a=9.292(2),b=27.231(8),c=8.308(2),V=2102.3(1.6),Z=4,Dc=1.42 g/cm3 ,A(MoKα)=0.71069,μ=7.2 cm-1,F(000)=920,T=296K,final R=0.043 and Rw=0.065 for 1889 observed reflections with I>3.0 σ(I).The geometry around the central Mo(0) atom in the title complex is a distorted octahedron with S,N atoms of pyridine-2-thiolato ligand(pyS) and four C atoms from carbonyls,the bond distances of Mo-S and Mo-N are 2.637 and 2- 273 , respectively. |
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| Keywords: | synthesis crystal structure molybdenum complex pyridine-2-thiolato |
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