Manganese(III) acetate mediated oxidation of aporphines: a convenient and useful synthesis of oxoaporphines |
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| Authors: | Om V. Singh Wei-Jan Huang |
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| Affiliation: | School of Pharmacy, College of Medicine, National Taiwan University, 1 Jen-Ai Road, Sec. 1, Taipei 100, Taiwan, ROC |
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| Abstract: | Manganese(III) acetate mediated oxidation of aporphines to oxoaporphines is described. The developed methodology was conveniently applied for the synthesis of naturally occurring oxoaporphine alkaloids, oxoglaucine, and atheroline, starting from commercially available boldine. |
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| Keywords: | Isoquinoline alkaloids Aporphines Manganese(III) acetate Iodobenzene diacetate Oxoaporphine Oxoglaucine Atheroline |
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