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Dynamic Fatigue Behavior of Natural Rubber Reinforced with Nanoclay and Carbon Black
Authors:Liangliang Qu  Yijing Nie  Guangsu Huang  Gengsheng Weng  Jinrong Wu
Institution:State Key Laboratory of Polymer Materials Engineering , College of Polymer Science and Engineering, Sichuan University , Chengdu, P. R. China
Abstract:The dynamic fatigue behaviors of natural rubber (NR) filled with carbon black (CB) and both nanoclay (NC) and CB at same hardness was evaluated using the stepwise increasing strain test (SIST) and long-term testing. Compared with NR/CB composites, NR/CB/NC nanocomposites exhibited higher fatigue-limited strain, stronger dynamic stress relaxation, and longer compression fatigue life. By examining the fracture morphologies, nonlinear viscoelastic behavior, and hysteresis loss of filled NR, it was found that NR, synergisticly reinforced by NC and CB, exhibited improved anti-fatigue ability than NR filled with CB due to stronger filler–filler interactions between NC and CB (a local filler network) and the high aspect ratio and typical lamellar structure of NC.
Keywords:carbon black  dynamic fatigue behavior  filler network  nanoclay  natural rubber
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