Rheological Behaviors of Polypropylene/Poly(1-butene) Blends |
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| Authors: | Huafeng Shao Shulei Wang Xia Dong |
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| Affiliation: | 1. Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics (Ministry of Education), Qingdao University of Science and Technology, Qingdao, Shandong, China;2. Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Chambroad Chemical Industry Research Institute Co., Ltd, Binzhou, China;3. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China |
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| Abstract: | The rheological behaviors of polypropylene (PP)/poly(1-butene) (PB) blends with homo-polypropylene (PP1) or impact polypropylene (PP2), a poly(propylene-co-ethylene) as the PP component were studied. With increasing of PB resin content for both PP/PB blends, the blends showed higher G'(ω), G''(ω) and η*(ω) at low frequencies but lower values at high frequencies which implied that the processability was improved. A two-phase morphology was observed through the various rheological responses, including G'(ω)-ω terminal region curves, Cole-Cole plots and the weighted relaxation spectra with the PB contents up to 40?wt%. With the same PB content, the rheological parameters of the PP2/PB blends were quite different from those of the PP1/PB, which can be attributed to the stronger interaction between PB chains and the ethylene-co-propylene copolymer in PP2. The impact strength of the PP2/PB blends was improved dramatically over that of the PP1/PB. The more significant toughening effect for the PP2/PB blends can be attributed to the special responses of its rheological behaviors. |
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| Keywords: | Polypropylene poly(1-butene) blends rheological behavior mechanical properties |
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