SiO2 Reinforced EVM/TPU Blends: Bound Rubber and Rheology Behavior |
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Authors: | Xinyan Shi Fei Zhao Junxue Zhai Shugao Zhao |
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Affiliation: | Key Laboratory of Rubber and Plastics , Qingdao University of Science and Technology, Ministry of Education , Qingdao, 266042, China |
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Abstract: | Silica is shown to be a more active filler than carbon black for the reinforcement of EVM/TPU blends. The static rheology of EVM/TPU blends is considerably influenced by a tightly bound rubber structure developing between the TPU and silica that was identified by a tetrahydrofuran extraction test and SEM observations. Dynamic rheology behavior corroborated the development of bound rubber and indicated the existence of the Payne effect because of filler-filler networks in the blends. The silica-TPU interaction is thermally unstable at 190°C and mechanically unstable at a shear frequency of 1 Hz. |
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Keywords: | EVM TPU silica bound rubber rheology behavior |
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