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Thermal and Tensile Properties of Epoxy Nanocomposites Reinforced by Silane-functionalized Multiwalled Carbon Nanotubes
Authors:Hee-Cheul Kim  Sun-Kuk Kim  Jeong Tai Kim  Kyong-Yop Rhee  John Kathi
Institution:1. Department of Architectural Engineering , Kyung Hee University , Yongin, Republic of Korea;2. Department of Mechanical Engineering , Kyung Hee University , Yongin, Republic of Korea
Abstract:Epoxy nanocomposites with unmodified multiwalled carbon nanotubes (u-MWCNTs) and silanized multiwalled carbon nanotubes (si-MWCNTs) were prepared by a cast molding method. The effects of 3-aminopropyltriethoxysilane functionalization of MWCNTs on thermal, tensile, and morphological properties of the nanocomposites were examined. The nanocomposites were characterized by thermogravimetric analysis, dynamic mechanical thermal analysis, and tensile testing. The results showed that epoxy composites based on si-MWCNTs showed better thermal stability, glass transition temperature, and tensile properties than the composites based on u-MWCNTs. These results prove the effect of silane functionalization on the interfacial adhesion between epoxy and MWCNTs. This was further confirmed by morphology study of fractured surfaces of nanocomposites by field emission scanning electron microscopy.
Keywords:epoxy  mechanical properties  multiwalled carbon nanotubes  nanocomposites  silanization  thermal properties
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