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Lattice orientation within stirring-induced crystals of polyethylene
Authors:A keller  F M willmouth
Institution:1. H. H. Wills Physics Laboratory , University of Bristol Royal Fort Bristol , England;2. H. H. Wills Physics Laboratory , University of Bristol Royal Fort Bristol , England;3. Plastics Division, I.C.I. Ltd. , Bessemer Road, Welwyn Garden City, Herts, England
Abstract:Micro-shish-kebab stirring-induced polyethylene crystals, as defined and described in the preceding paper, are flat, ribbon-shaped fibers. Selected area electron-diffraction techniques were used to determine the orientation of the crystal axes with respect to the external fiber shape. It has been shown that in addition to the crystal-lographic c-axis laying along the fiber direction, the normal to the ribbon plane is parallel to the crystallographic a-axis.
Keywords:Polypropylene  Chain microstructure  Flow pattern  Microcrystallinity
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