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Effect of Silanes on Mechanical and Thermal Properties of Silicone Rubber/EPDM Blends
Authors:Chen Zhang  Zhen Xiu Zhang  Kaushik Pal  Oe Gi Shin  Hyeon Choel Jo  Sung Hoon Lee
Affiliation:1. School of Nano and Advanced Materials Engineering , Gyeongsang National University , Gyeongnam, Jinju, South Korea;2. School of Material Science and Engineering , Shandong University , Jinan, China;3. Key Laboratory of Rubber-Plastics, Ministry of Education, Shandeng Provincial Key Laboratory of Rubber-Plastics , Qingdao University of Science and Technology , Qingdao, China;4. School of Nano and Advanced Materials Engineering , Gyeongsang National University , Gyeongnam, Jinju, South Korea;5. Pyung Hwa Industrial Co. Ltd. , Daegu City, South Korea;6. Hyundai Kia Motors Co. Ltd. , Seoul, South Korea
Abstract:The effect of four types of silane coupling agents on the mechanical and thermal properties of silicone rubber and ethylene–propylene–diene monomer (M-class) rubber (EPDM) blends is studied, namely, isobutyltriethoxysilane (BUS), acryloxypropyltriethoxysilane (ACS), aminopropyltriethoxysilane (AMS), and vinyltriethoxysilane (VIS). ACS and VIS increase the crosslink density of the blends, which results in higher tensile strength, modulus, and thermal stability, but lower elongation at break compared with the other silanes. However, the blend containing BUS shows highest tanδ in the temperature range of 45°C to 200°C. Thermogravimetric analysis shows two steps of degradation for all the samples, but little difference with the varied silanes.
Keywords:dynamic mechanical properties  EPDM  mechanical properties  silane  silicone rubber  thermal properties
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