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N,N′‐Bis(arylmethylidene)arylmethanediamines: Suitable Precursors for the Synthesis of 1‐Pyrroline Derivatives
Authors:Abdolali Alizadeh  Leila Moafi
Affiliation:1. +98‐21‐88006631+98‐21‐88006544;2. Department of Chemistry, Tarbiat Modares University, Tehran, Iran
Abstract:A simple and appropriate procedure for the synthesis of 4,5‐dihydro‐5‐hydroxy‐3H‐pyrrole‐3,3‐dicarbonitrile derivatives is reported. The advantages of this method are one‐pot conditions, high yield of products, short reaction times, and no need of metal catalyst. The structures are confirmed spectroscopically (IR, 1H‐ and 13C‐NMR, and EI‐MS) and by elemental analyses. A plausible mechanism for this reaction is proposed (Scheme 2).
Keywords:N‐Containing heterocycles  1‐Pyrroline  Phenacylbromide  Multicomponent reaction  Arylmethanediamines, N,N′  ‐bis(arylmethylidene)‐
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