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有机同系物性质的递变规律研究
引用本文:聂长明,范明舫. 有机同系物性质的递变规律研究[J]. 有机化学, 2000, 20(1): 122-130
作者姓名:聂长明  范明舫
作者单位:中南工学院化学工程系,衡阳421001
摘    要:以有机同系物结构重复单元数值连续变化为模型,得到同系物行质递变的两个基本规律:P=a+bn和P=c+kln(n+a/n+b),a,b,c,k均为常数,n为结构重复单元数值,P为同系物的物性。一般地,加和型性能遵守直线变化规律,而结构型和凝聚型性能遵守同系对数线性规律。

关 键 词:同系物  递变规律  物理化学性能  同系线性规律
修稿时间:1999-02-02

Regularity of physicochemical properties for homologous organic compounds
Nie Chang-Ming,Fan Ming-Fang. Regularity of physicochemical properties for homologous organic compounds[J]. Chinese Journal of Organic Chemistry, 2000, 20(1): 122-130
Authors:Nie Chang-Ming  Fan Ming-Fang
Affiliation:Nie Chang- Ming,Fan Ming- Fang(Department of Chemical Engineering, Central- South Institute of Technology, 421001 Hengyang)
Abstract:With the model that the number of repeating units of the homologous series varies successively, two fundamental relationships have been developed:P = a bn and P = c kln n a/n bwhere a,b,c,k all refer to the constants, n to the number of repeating units, P to the properties for ho-mogolous series. Generally, additive type properties conform to the linear relationship, and the structural - type properties and condened - type properties to the homologous logarithmic linear relationship.
Keywords:homologous organic compounds   physical property   homologous logarithmic linear law
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