| 水介质中可控/活性自由基聚合的研究进展 |
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| 引用本文： | 彭慧,沈艳华,柯勇,程时远.水介质中可控/活性自由基聚合的研究进展[J].高分子通报,2003(1):43-52. |
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| 作者姓名： | 彭慧 沈艳华 柯勇 程时远 |
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| 作者单位： | 湖北大学化学与材料科学学院,武汉,430062 |
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| 摘 要： | 综述了均相水溶液体系和分散，悬浮，乳液及微乳液等非均匀相水溶液体系中的可控／活性自由基聚合的研究现状，对一些最常见的可控自由基聚合方法，如氮氧调控聚合，原子转移自由基聚合和可逆加成－继裂链转移聚合方法的聚合情况进行了详细的介绍，展望了水介质中可控／活性自由基聚合的发展方向及前景。
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| 关 键 词： | 水溶液 可控／活性自由基聚合 原子转移自由基聚合 可逆可成－断裂链转移 |
The Development of Controlled/living Radical Polymerization in Aqueous Media |
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| PENG Hui,SHEN Yan-hua,KE Yong,CHENG Shi-yuan.The Development of Controlled/living Radical Polymerization in Aqueous Media[J].Polymer Bulletin,2003(1):43-52. |
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| Authors: | PENG Hui SHEN Yan-hua KE Yong CHENG Shi-yuan |
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| Abstract: | Controlled/living radical polymerizations carried out in the presence of water have been examined.These aqueous systems include both the homogeneous and the various heterogeneous,namely dispersion,suspension,emulsion and miniemulsion,Among them,the most common methods allowing control of the radical polymerization,such as nitroxide-mediated polymerization,atom transfer radical polymerization and reversible addition-fragmentation transfer,are presented in detail.Good prospects for controlled/living radical polymerization in aqueous media are also shown. |
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| Keywords: | Aqueous solution Controlled/living radical polymerization Nitroxide Atom transfer radical polymerization Reversible addition-fragmentation transfer |
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