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The effect of self-association on the reactivity of calix[4]resorcinolarene anions with respect to esters of phosphorus acids
Authors:I. S. Ryzhkina  L. A. Kudryavtseva  A. R. Burilov  E. Kh. Kazakova  A. I. Konovalov
Affiliation:(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan', Russian Federation
Abstract:The kinetics of reactions of amphiphilic anions derived from calix[4]resorcinolarenes and their aggregates withp-nitrophenyl esters of phosphorus acids were studied by spectrophotometry. The effect of hydrophobicity of the substituent R and of the composition of aqueous dimethylformamide solvent (30, 50, 80% (v/v) DMF) on these processes was investigated. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 275–279, February, 1998.
Keywords:kinetics  self-association  micelle formation  calix[4]resorcinolarenes  esters of phosphorus acids
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