The effect of self-association on the reactivity of calix[4]resorcinolarene anions with respect to esters of phosphorus acids |
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Authors: | I. S. Ryzhkina L. A. Kudryavtseva A. R. Burilov E. Kh. Kazakova A. I. Konovalov |
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Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan', Russian Federation |
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Abstract: | The kinetics of reactions of amphiphilic anions derived from calix[4]resorcinolarenes and their aggregates withp-nitrophenyl esters of phosphorus acids were studied by spectrophotometry. The effect of hydrophobicity of the substituent R and of the composition of aqueous dimethylformamide solvent (30, 50, 80% (v/v) DMF) on these processes was investigated. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 275–279, February, 1998. |
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Keywords: | kinetics self-association micelle formation calix[4]resorcinolarenes esters of phosphorus acids |
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