Solid-phase chemical transformations in molybdate systems |
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| Authors: | B. G. Bazarov R. F. Klevtsova Zh. G. Bazarova S. F. Solodovnikov S. T. Bazarova K. N. Fedorova |
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| Affiliation: | (1) Baikal Institute of Environmental Science, Siberian Division, Russian Academy of Sciences, 6 ul. Sakh'yanovoi, 670047 Ulan-Ude, Russian Federation;(2) Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | The ternary salt systems M2MoO4−AMoO4−Zr(MoO4)2 (M=K, Tl; A=Mg, Mn, Ni, Co, Cu, Zn, Cd) in a sub-solidus region were studied. New ternary molybdates with the M5A0.5Zr1.5(MoO4)6 and MA0.5Zr0.5(MoO4)2 compositions were synthesized by solid-phase reactions in these systems. The crystallographic and thermal characteristics of the compounds were found. The electrical properties of potassium—manganese—zirconium molybdates were studied. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1036–1039, June, 1999. |
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| Keywords: | ternary molybdates of uni-, bi-, and tetravalent elements crystallographic thermal and electrical properties |
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