Structure and properties of cellulose/poly(N‐isopropylacrylamide) hydrogels prepared by IPN strategy |
| |
Authors: | Chunyu Chang Kai Han Lina Zhang |
| |
Affiliation: | Department of Chemistry, Wuhan University, Wuhan, China |
| |
Abstract: | Interpenetrating polymer network (IPN) strategy was developed to fabricate novel hydrogels composed of cellulose and poly(N‐isopropylacrylamide) (PNIPAAm) with high mechanical strength and adjustable thermosensitivity. Cellulose hydrogels were prepared by chemically cross‐linking cellulose in NaOH/urea aqueous solution, which were employed as the first network. The second network was subsequently obtained by in situ polymerization/cross‐linking of N‐isopropylacrylamide in the cellulose hydrogels. The results from FTIR and solid 13C NMR indicated that the two networks co‐existed in the IPN hydrogels, which exhibited uniform porous structure, as a result of good compatibility. The mechanical and swelling properties of IPN hydrogels were strongly dependent on the weight ratio of two networks. Their temperature‐sensitive behaviors and deswelling kinetics were also discussed. This work created double network hydrogels, which combined the advantages of natural polymer and synthesized PNIPAAm collectively in one system, leading to the controllable temperature response and improvement in the physical properties. Copyright © 2009 John Wiley & Sons, Ltd. |
| |
Keywords: | cellulose interpenetrating polymer network hydrogel mechanical strength poly(N‐isopropylacrylamide) thermosensitivity |
|
|