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Synthesis and microwave absorbing properties of poly(3,4‐ethylenedioxythiophene) (PEDOT) microspheres
Authors:Xunwei Ni  Xiujie Hu  Shuyun Zhou  Chenghua Sun  Xiaoxia Bai  Ping Chen
Institution:1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China;3. Key laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China
Abstract:Poly(3,4‐ethylenedioxythiophene) (PEDOT) solid and hollow microspheres were successfully synthesized by simply adjusting the concentration of 3,4‐ethylenedioxythiophene (EDOT) and the molar ratio of EDOT to ammonium persulfate (APS) (represented by (EDOT)/(APS)), respectively. Microwave absorbing properties of PEDOT microspheres with tunable reflection loss (RL) and microwave frequency band were described in detail. The relationships between the conductivity and RL of PEDOT microspheres were also discussed. Copyright © 2010 John Wiley & Sons, Ltd.
Keywords:conducting polymers  hollow microspheres  microwave absorbing properties  poly(3  4‐ethylenedioxythiophene) (PEDOT)
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