Iodocyclization reactions for the desymmetrization of cyclohexa-1,4-dienes |
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Authors: | Butters M Elliott M C Hill-Cousins J Paine J S Walker J K E |
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Institution: | School of Chemistry, Cardiff University, Park Place, Cardiff, CF10 3AT, UK. |
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Abstract: | Fifteen examples are presented showing that various modes of cyclization (5-endo, 5-exo, 6-endo, 6-exo, and 7-endo) can be used for the desymmetrization of cyclohexa-1,4-dienes. All take place with complete diastereocontrol and good yield. |
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