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Zur Reaktion von Chlorsilanen mit Dialkylphosphonaten
Authors:Kurt Kellner  Lutz Rodewald
Affiliation:(1) Fachbereich Chemie, Martin-Luther-Universität Halle-Wittenberg, D-O-4010 Halle (S.), Bundesrepublik Deutschland
Abstract:Summary The reaction of dichlorodiorganosilanes with dialkylphosphonates is described. Depending on the reaction conditions diorganosilyl-bis(O-alkylphosphonates)R2Si[OP(O)H(ORprime)]2 and diorganosilylphoshonates [-R2Si-OP(O)HO-], respectively, are formed.Using this type of reaction, O-alkoxysilyl Oprime-alkylphosphonates can be obtained both by interaction of dialkylphosphonates with dichlorodialkoxysilanes or chlorodialkoxyalkylsilanes, respectively.
Herrn Professor Dr. E. Hengge anläßlich seines 60. Geburtstages gewidmet
Keywords:Dialkylphosphonates  Dichlorodialkoxysilanes  Dichlorodiorganosilanes  O-Silyl O  /content/q437hn6064m8m321/xxlarge8242.gif"   alt="  prime"   align="  BASELINE"   BORDER="  0"  >-alkylphosphonates
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