(1) Fachbereich Chemie, Martin-Luther-Universität Halle-Wittenberg, D-O-4010 Halle (S.), Bundesrepublik Deutschland
Abstract:
Summary The reaction of dichlorodiorganosilanes with dialkylphosphonates is described. Depending on the reaction conditions diorganosilyl-bis(O-alkylphosphonates)R2Si[OP(O)H(OR)]2 and diorganosilylphoshonates [-R2Si-OP(O)HO-], respectively, are formed.Using this type of reaction, O-alkoxysilyl O-alkylphosphonates can be obtained both by interaction of dialkylphosphonates with dichlorodialkoxysilanes or chlorodialkoxyalkylsilanes, respectively.
Herrn Professor Dr. E. Hengge anläßlich seines 60. Geburtstages gewidmet