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Electron spin resonance detection and identification of nitrogen centers in nanodiamonds
Authors:P G Baranov  I V Il’in  A A Soltamova  A Ya Vul’  S V Kidalov  F M Shakhov  G V Mamin  S B Orlinskii and M Kh Salakhov
Institution:(1) Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia;(2) Federal Center of Shared Usage for Physicochemical Measurements, Kazan State University, ul. Kremlevskaya 18, Kazan, 420008, Russia
Abstract:Individual nitrogen centers N0 and nitrogen pairs N 2 + have been detected and identified in natural diamond nanocrystals by means of the high-frequency electron spin resonance method. The N0 nitrogen centers have been observed in synthetic diamond nanocrystallites with a size of less than 10 nm produced by high-temperature high-pressure sintering of detonation nanodiamonds. Thus, the possibility of the stable state of impurity nitrogen atoms in diamond nanoparticles has been demonstrated.
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