Effect of inorganic electrolyte concentration on anionic-cationic adsorption films Part 1. Decylpyridinium chloride + sodium octylsulphonate + sodium chloride |
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Authors: | D. Góralczyk B. Woligóra |
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Affiliation: | (1) Present address: Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, Kracow, Poland |
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Abstract: | The effect of NaCl on simultaneous adsorption of decylpyridinium chloride (R10PyCl) and sodium octylsulphonate (R8SO3Na) on the free surface of their aqueous solutions has been examined. The surface excess of each component was determined on the basis of a suitable form of the Gibbs adsorption equation. The ionic strength effect on the adsorption of particular components of mixtures, as well as on the composition of anionic-cationic films adsorbed from equimolar solutions, is small. This is due to little difference in surface activity of surfactants investigated. |
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Keywords: | Decylpyridinium chloride sodium octylsulphonate surface tension anion-ic-cationicadsorption films |
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