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D-氨基葡萄糖与Sm^3+和Eu^3+离子配合物的合成和表征
引用本文:仇立干,王茂元. D-氨基葡萄糖与Sm^3+和Eu^3+离子配合物的合成和表征[J]. 化学研究与应用, 2008, 20(6): 752-755
作者姓名:仇立干  王茂元
作者单位:江苏省滩涂生物资源与环境保护重点建设实验室,盐城师范学院化学化工学院,江苏,盐城,224051
摘    要:D-氨基葡萄糖(2氨-基-2脱-氧-D葡-萄糖,简称GLCN)是甲壳素或壳聚糖的最终水解产物。由于其分子内含有多个反应中心(-OH,-NH2),且无毒、水溶性好,易与多种金属离子配位,而用于贵金属回收、工业废水处理等生态和环境保护方面;由于其与金属离子形成的配合物水溶性好、低毒、甚至无

关 键 词:D-氨基葡萄糖盐酸盐  稀土离子  配合物  表征
文章编号:1004-1656(2008)06-0752-04
修稿时间:2007-09-04

Synthesis and characterization of the coordination compounds of Sm3+and Eu3+ ions with D-glucosamine
QIU Li-gan,WANG Mao-yuan. Synthesis and characterization of the coordination compounds of Sm3+and Eu3+ ions with D-glucosamine[J]. Chemical Research and Application, 2008, 20(6): 752-755
Authors:QIU Li-gan  WANG Mao-yuan
Abstract:The coordination compounds were synthesized by the rare earth ions(Sm3 ,Eu3 ) with D-glucosamine hydrochloride(GAH).GAH and its coordination compounds were characterized by IR,UV-vis and TG-DSC respectively.The results indicated that both the rare earth ions formed the steady coordination compounds with D-glucosamine.
Keywords:D-glucosamine hydrochloride  rare earth ions  coordination compound  characterization
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