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Nano‐sized silver crystals and their dispersion over α‐alumina for ethylene epoxidation
Authors:S. Sadegh Hassani  M. R. Ghasemi  M. Rashidzadeh  Z. Sobat
Abstract:Ethylene oxide catalyst is a high metal loading catalyst, in which silver crystals is impregnated on α‐Al2O3 support. In this type of catalyst, metal dispersion plays an important role on catalyst selectivity for desired products. In this work, silver nitrate and silver oxide together with oxalic and lactic acid as the raw materials were used with different impregnation techniques to make catalysts with high silver content and dispersion. It is also known that the use of promoters affect the metal dispersion on the catalyst support and for that cesium was used as the promoter to improve the silver crystal dispersion. Physical and chemical characteristics of the prepared catalysts, i.e., surface area, pore volume, silver content, nano‐sized silver crystals and their dispersion were measured using BET method, Atomic Absorption Spectroscopy, X‐ray diffraction and TEM. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Keywords:nano‐sized silver crystals  crystal size  dispersion  ethylene oxide catalyst  cesium
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