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A Triphenylamine‐Based Conjugated Polymer with Donor‐π‐Acceptor Architecture as Organic Sensitizer for Dye‐Sensitized Solar Cells
Authors:Wei Zhang  Zhen Fang  Mingjuan Su  Mark Saeys  Bin Liu
Abstract:A conjugated polymer containing an electron donating backbone (triphenylamine) and an electron accepting side chain (cyanoacetic acid) with conjugated thiophene units as the linkers has been synthesized. Dye‐sensitized solar cells (DSSCs) are fabricated utilizing this material as the dye sensitizer, resulting a typical power conversion efficiency of 3.39% under AM 1.5 G illumination, which represents the highest efficiency for polymer dye‐sensitized DSSCs reported so far. The results show the good promise of conjugated polymers as sensitizers for DSSC applications.
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Keywords:conjugated polymers  dyes/pigments  modeling  photochemistry  synthesis
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