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High‐resolution stimulated Raman spectroscopy and analysis of the 2ν10 overtone symmetric motion of C2H4
Authors:M Loroo  D Bermejo  M Rotger  V Boudon
Abstract:The high‐resolution stimulated Raman spectrum of the 2ν10 band located at 1664.16 cm−1 of C2H4 has been reanalyzed, thanks to the tensorial formalism developed in Dijon for X2Y4 asymmetric‐top molecules. A total of 191 lines were assigned and fitted as a single band without including perturbations such as Fermi or Coriolis coupling constants. We obtained a global root mean square deviation of 8.5 × 10−3 cm−1. Further investigations are required to include interactions with the ν2 and ν7 + ν10 bands. Copyright © 2009 John Wiley & Sons, Ltd.
Keywords:ethylene  high‐resolution stimulated Raman spectroscopy  tensorial formalism
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