A novel inorganic-organic compound: Synthesis and structural characterization of tin(II) phenylbis(phosphonate), Sn2(PO3C6H4PO3) |
| |
Authors: | Ayyappan Subbiah |
| |
Institution: | Department of Chemistry, Texas A&M University, Clearfield Research Group, TAMU 3255, P.O. Box 30012, College Station, TX 77842-3012, USA |
| |
Abstract: | A novel tin(II) phenylbis(phosphonate) compound has been synthesized hydrothermally and its structure has been determined by single crystal X-ray diffraction. The structure is monoclinic, space group P21/c (no. 14), a=4.8094(4), b=16.2871(13), ; β=106.292(6)°, , Z=2. The three-dimensional structure consists of 3-coordinated tin and 4-coordinated phosphorus double layers separated (pillared) by phenyl rings. These phenyl rings are placed 4.8 Å apart along the a-axis in the structure resulting in lower surface area (∼14 m2/g). The porosity has been increased by replacing phenyl groups by methyl groups (∼31 m2/g). |
| |
Keywords: | Inorganic-organic hybrid Hydrothermal synthesis |
本文献已被 ScienceDirect 等数据库收录! |
|