Comparison of single and multiple scattering approaches for the simulation of limb-emission observations in the mid-IR

The validity of single scattering radiative transfer calculations for simulation of limb-emission measurements of clouds in the mid-infrared spectral region was investigated by comparison with a multiple scattering model. For in limb direction optically thin clouds, like polar stratospheric clouds, errors of the single scattering scheme range below 3%. For optically thick clouds deviations are below 3% in case of low single scattering albedo (ω₀=0.24) increasing up to 10-30% for ω₀=0.84. Clouds which are optically thick in limb, but thin in nadir direction, can cause limb radiances which are by a factor of 1.7 higher than the blackbody radiance at cloud altitude.