| 聚对苯二甲酸乙二酯／热致液晶聚合物共混体系中液晶组分的诱导结晶效应 |
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| 引用本文： | 马洪涛,许家瑞,麦堪成,曾汉民.聚对苯二甲酸乙二酯／热致液晶聚合物共混体系中液晶组分的诱导结晶效应[J].高分子学报,1995,0(3):327-331. |
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| 作者姓名： | 马洪涛 许家瑞 麦堪成 曾汉民 |
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| 作者单位： | 中山大学材料科学研究所 |
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| 基金项目： | 国家高技术新材料领域青年基金,国家教委博士点专项基金 |
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| 摘 要： | 用差示扫描量热法对聚对苯二甲酸乙二酯（ＰＥＴ）／热致液晶高分子（ＬＣＰ）共混体系的等温和非等温结晶行为进行了研究．结果表明，由于液晶组分的加入，共混体系中ＰＥＴ的结晶速率和结晶度均得到提高．说明ＬＣＰ具有ＰＥＴ结晶成核剂的作用．在较低的ＬＣＰ组分含量下（～２ｗｔ％），这一效果最为明显，说明ＬＣＰ是以很小的微区或某些ＬＣＰ分子链介晶微束的形式对ＰＥＴ的结晶起成核剂的作用．
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| 关 键 词： | 热致液晶聚合物，聚对苯二甲酸乙二酯，共混，诱导结晶 |
| 收稿时间： | 1993-11-17 |
INDUCTION EFFECTS OF LCP COMPONENT ON THE CRYSTALLIZATION OF PET IN THE BLENDS |
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| MA Hong-tao,XU Jia-rui,MAI Kan-cheng,ZENG Han-min.INDUCTION EFFECTS OF LCP COMPONENT ON THE CRYSTALLIZATION OF PET IN THE BLENDS[J].Acta Polymerica Sinica,1995,0(3):327-331. |
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| Authors: | MA Hong-tao XU Jia-rui MAI Kan-cheng ZENG Han-min |
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| Institution: | Materials Science Institute; Zhongshan University; Guangzhou 510275 |
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| Abstract: | he isothermal and non-isothermal crystallization behaviors of blends o f thermotropic liquid crystalline polyester (LCP) and PET have been studied.The crystallization rate and crytallinity of PET in The blends were signifcantly higher than that of pure PET, which suggests that LCP component acts as a nucleating agent for crystallization of PET. The most efficient nucleation is found at a low content of LCP component (about 2 wt%LCP), implying that the microdomain or aggregating segments of LCP would be the nuclei for PET. |
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| Keywords: | Thermotropic liquid crystalline polymer Polyethylene terephthalate Blending Induced crystallization |
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