Refined crystal structure of iron-rich triclinic astrophyllite |
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Authors: | N. A. Yamnova Yu. K. Egorov-Tismenko I. V. Zlykhenskaya A. P. Khomyakov |
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Affiliation: | (1) Moscow State University, Vorob’evy gory, Moscow, 119899, Russia;(2) Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Russian Academy of Sciences, ul. Veresaeva 15, Moscow, 121327, Russia |
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Abstract: | Crystal structure of Fe-rich triclinic astrophyllite K2NaFe7 [Ti2Si8O26F](OH)4 is refined (a Syntex P $bar 1$ automatic diffractometer, 3809 reflections, 2θ/θ scan, R = 0.041): a = 5.365(2), b = 11.88(1), c = 21.03(2) Å, α = 84.87(6)°, β = 92.25(5)°, γ = 103.01(4)°, sp. gr. A $bar 1$ , Z = 2, d calcd = 3.29 g/cm3. The refined structure is identical to that reported earlier. The structure is built by three-layer TOT sheets in which an O layer of Fe-octahedra is sandwiched between the T layers consisting of Si-tetrahedra and Ti-octahedra. It is established that differently chosen unit cells of the mineral are interrelated. |
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