| 银(Ⅰ)、锌(Ⅱ)与2，2′-(2-氨基-苯氧基)乙醚配合物的合成及晶体结构 |
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| 作者姓名： | 朱兴城 丁亚洲 张奇龙 朱必学 |
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| 作者单位： | 贵州大学,贵州省大环化学及超分子化学重点实验室,贵阳,550025 |
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| 基金项目： | 国家自然科学基金，贵州省国际合作重点项目 |
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| 摘 要： | The compound 2,2′-(2-amino-phenoxy)-ether[L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n (2) respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn(Ⅱ) linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube. CCDC: 748592, 1; 748594, 2.
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| 关 键 词： | 2，2′-(2-氨基-苯氧基)乙醚； 配合物； 晶体结构 |
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