Rate constant for water loss from low-spin iron(II) in aquapentacyanoferrate(II) |
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| Authors: | Muriel Fernando Sánchez Francisco Burgess John |
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| Institution: | (1) Departamento de Química Física, Universidad de Sevilla, 41012 Sevilla, Spain;(2) Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK |
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| Abstract: | Rate constants for the reaction of Fe(CN)5(H2O)]–3 with Co(NH3)5(pyrazine)]3+ have been analysed on the basis of a pre-association equilibrium constant and a rate constant for the subsequent ligand interchange. The latter represents an unusual parameter, a rate constant for water loss from a low-spin iron(II) centre. |
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