Effect of free phosphine on the reactivity of phosphine-containing rhodium(I) complexes |
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| Authors: | T. A. Andreeva V. I. Makarov G. I. Skubnevskaya N. M. Bazhin |
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| Affiliation: | (1) Institute of Inorganic Chemistry, Kemerovo;(2) Institute of Chemical Kinetics and Combustion, Novosibirsk, USSR |
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| Abstract: | The photolysis products of SO2-pentane-NO mixtures are N2O, H2O and a compound designated as RNO. Kinetic data obtained by OC method confirm the previously proposed scheme of photolysis. Also studied was the photolysis of SO2, NO and cyclohexane mixtures. From comparison of spectral characteristics of RNO and its analog 2-methyl-2-nitrosopropane, the probable structure of RNO is suggested.
            SO2-   -NO       N2O, H2O  ,    RNO.  ,   ,    .  SO2 NO  .  RNO 2--2- RNO.
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