Tributylphosphine: a remarkable promoting reagent for the ring-opening reaction of aziridines |
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| Authors: | Hou Xue-Long Fan Ren-Hua Dai Li-Xin |
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| Institution: | Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis and State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Road, Shanghai 200032, China. xlhou@pub.sioc.ac.cn |
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| Abstract: | Tributylphosphine was found to be an effective promoting reagent for ring opening of a variety of aziridines and nucleophiles to produce anti-bifunctional products in good to excellent yield. The study showed that the reaction is initiated through the attack of tributylphosphine as a nucleophile at the carbon atom of the aziridine ring. |
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