| 纳米ZnO修饰电极的制备及其对血红蛋白, 细胞色素c的直接电化学研究 |
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| 引用本文： | 张成林,刘梅川,李平,鲜跃仲,程欲晓,张芬芬,王晓丽,金利通. 纳米ZnO修饰电极的制备及其对血红蛋白, 细胞色素c的直接电化学研究[J]. 中国化学, 2005, 23(2): 144-148. DOI: 10.1002/cjoc.200590144 |
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| 作者姓名： | 张成林 刘梅川 李平 鲜跃仲 程欲晓 张芬芬 王晓丽 金利通 |
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| 作者单位： | [1]DepartmentofChemistry,EastChinaNormalUniversity,Shanghai200062,China [2]DepartmentofChemistry,EastChinaNormalUniversity,Shanghai200062,China／／StateKeyLaboratoryofChemo／BiosensingandChemometrics,HunanUniversity,Changsha,Hunan410082,China |
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| 摘 要： | A novel electrochemical method as a sensitive and convenient technique for the determination of heme proteins based on their interaction with ZnO nanorods was developed. A ZnO nanorod modified glassy carbon electrode (ZnO/GCE) was prepared and the electrochemical behaviors of heme proteins, such as hemoglobin (HB) and cytochrome c (Cyt-c), on this modified electrode have been studied. The results showed that both HB and Cyt-c could be oxidized on the modified electrode and the oxidation currents were linear to the concentrations of the analytes in aqueous solutions. In addition, the results of flow injection analysis (FIA) further suggested the high stability and reproducibility of the ZnO nanorod modified electrode. So this method can be applied to the determination of HB and Cyt-c in biological systems.
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| 关 键 词： | ZnO 纳米棒 改性电极 血色素 细胞色素c 电化学测定 |
| 收稿时间： | 2004-05-31 |
| 修稿时间： | 2004-10-18 |
Fabrication of ZnO Nanorod Modified Electrode and Its Application to the Direct Electrochemical Determination of Hemoglobin and Cytochrome c |
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| Zhang Cheng‐Lin,Liu Mei‐Chuan,Li Ping,Xian Yue‐Zhong,Cheng Yu‐Xiao,Zhang Fen‐Fen,Wang Xiao‐Li,Jin Li‐Tong. Fabrication of ZnO Nanorod Modified Electrode and Its Application to the Direct Electrochemical Determination of Hemoglobin and Cytochrome c[J]. Chinese Journal of Chemistry, 2005, 23(2): 144-148. DOI: 10.1002/cjoc.200590144 |
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| Authors: | Zhang Cheng‐Lin Liu Mei‐Chuan Li Ping Xian Yue‐Zhong Cheng Yu‐Xiao Zhang Fen‐Fen Wang Xiao‐Li Jin Li‐Tong |
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| Abstract: | A novel electrochemical method as a sensitive and convenient technique for the determination of heme proteins based on their interaction with ZnO nanorods was developed. A ZnO nanorod modified glassy carbon electrode (ZnO/GCE) was prepared and the electrochemical behaviors of heme proteins, such as hemoglobin (HB) and cytochrome c (Cyt‐c), on this modified electrode have been studied. The results showed that both HB and Cyt‐c could be oxidized on the modified electrode and the oxidation currents were linear to the concentrations of the analytes in aqueous solutions. In addition, the results of flow injection analysis (FIA) further suggested the high stability and reproducibility of the ZnO nanorod modified electrode. So this method can be applied to the determination of HB and Cyt‐c in biological systems. |
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| Keywords: | ZnO/GCE hemoglobin cytochrome c direct electrochemical determination |
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