Fluorine-free organoxenon chemistry: HXeCCH,HXeCC, and HXeCCXeH |
| |
Authors: | Khriachtchev Leonid Tanskanen Hanna Lundell Jan Pettersson Mika Kiljunen Harri Räsänen Markku |
| |
Institution: | Department of Chemistry, FIN-00014 University of Helsinki, Finland. Leonid.Khriachtchev@Helsinki.Fi |
| |
Abstract: | Three novel Xe-containing organic compounds, HXeCCH, HXeCC (open-shell species), and HXeCCXeH, are identified using infrared absorption spectroscopy. They are prepared in a low-temperature Xe matrix using UV photolysis of acetylene and subsequent annealing at 40-45 K. The experimental observations are supported by extensive ab initio calculations. This work demonstrates a new way to activate the H-Ctbd1;C- group without use of XeF(2), which can extend the range of organoxenon compounds. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|