An analytical expression for the specific capacity of lithium ion cells

The concentration of lithium ions in the cathode of lithium ion cells has been obtained by solving the materials balance equation $$\frac{{\partial c}}{{\partial t}} = \varepsilon ^{1/2} D\frac{{\partial ^2 c}}{{\partial x^2 }} + \frac{{aj_n (1--t_ + )}}{\varepsilon }$$ by Laplace transform. On the assumption that the cell is fully discharged when there are zero lithium ions at the current collector of the cathode, the discharge timet _d is obtained as $$\tau = \frac{{r^2 }}{{\pi ^2 \varepsilon ^{1/2} }}\ln \left {\frac{{\pi ^2 }}{{r^2 }}\left( {\frac{{\varepsilon ^{1/2} }}{J} + \frac{{r^2 }}{6}} \right)} \right]$$ which, when substituted into the equationC=It _d /M, whereI is the discharge current andM is the mass of the separator and positive electrode, an analytical expression for the specific capacity of the lithium cell is given as $$C = \frac{{IL_c ^2 }}{{\pi {\rm M}D\varepsilon ^{1/2} }}\ln \left {\frac{{\pi ^2 }}{2}\left( {\frac{{FDc_0 \varepsilon ^{3/2} }}{{I(1 - t_ + )L_c }} + \frac{1}{6}} \right)} \right]$$