Synthetic studies toward the construction of the cis-decalin portion of superstolides A and B. Application of a sequential double michael reaction and an anionic oxy-Cope rearrangement |
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| Authors: | Hua Zhengmao Yu Wensheng Su Mei Jin Zhendong |
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| Institution: | Division of Medicinal and Natural Products Chemistry, College of Pharmacy, The University of Iowa, Iowa City, 52242, USA. |
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| Abstract: | A highly convergent strategy for the asymmetric synthesis of the cis-decalin portion of the antitumor macrolide superstolide A was developed. The key reactions in our approach involve a sequential double Michael reaction and an anionic oxy-Cope rearrangement. |
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