Allylation of 1-phenyl-1-propyne with N- and O-pronucleophiles using polymer supported triphenylphosphine palladium complex as a heterogeneous and recyclable catalyst |
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Authors: | Yogesh S. WaghDinesh N. Sawant Kishor P. DhakeKrishna M. Deshmukh Bhalchandra M. Bhanage |
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Affiliation: | Department of Chemistry, Institute of Chemical Technology, N. Parekh Marg, Matunga, Mumbai 400 019, India |
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Abstract: | Simple methodology for the allylation of various N- and O-pronucleophiles with 1-phenyl-1-propyne as an allylating agent, using PS-TPP-Pd (polymer supported triphenylphosphine palladium) as a highly active heterogeneous recyclable catalyst has been developed. The protocol is applicable for a wide variety of hindered and functionalized aromatic amines, alcohols, and carboxylic acids. The catalyst exhibited remarkable catalytic activity for five consecutive recycles. |
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Keywords: | Allylation Pronucleophiles Alkynes Palladium Heterogeneous catalyst |
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