| 希土(Ⅲ)噻吩甲酰三氟丙酮和BipyO2/PhenNO三元配合物的合成和表征 |
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| 作者姓名： | 成义祥 徐端钧 徐元植 |
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| 作者单位： | 浙江大学化学系，杭州 310027,浙江大学化学系，杭州 310027,浙江大学化学系，杭州 310027 |
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| 摘 要： | The new ternary complexes of RE(TTA)3(BipyO2)·H2O and RE(TTA)3 (PhenNO)(where RE=Sm, Eu, Gd; TTA=thenoyltrifluoroacetonate; BipyO2=2,2′-bipyridine-N,N′-dioxide; PhenNO=1,10-phenanthroline-N-oxide)have been synthesized. The composition and properties of complexes were studied by elemental analysis, UV spectrum, IR spectrum, DTA-TG and fluorescence spectrum. The effect of solvent on fluorescent intensity is discussed.
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| 关 键 词： | 希土 三元配合物 噻吩甲酰三氟丙酮 荧光光谱 |
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