| Mo(W)-Cu(Ag)-S簇合物的拓扑学研究 |
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| 引用本文： | 金琼花,刘建明,忻新泉,陶荣达.Mo(W)-Cu(Ag)-S簇合物的拓扑学研究[J].无机化学学报,1997,13(1):95-100. |
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| 作者姓名： | 金琼花 刘建明 忻新泉 陶荣达 |
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| 作者单位： | 南京大学配位化学研究所，南京 210093;北京大学数学系，北京 100871,南京大学配位化学研究所，南京 210093;北京大学数学系，北京 100871,南京大学配位化学研究所，南京 210093;北京大学数学系，北京 100871,南京大学配位化学研究所，南京 210093;北京大学数学系，北京 100871 |
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| 摘 要： | 本文给出了一种由Mo(W)-Cu(Ag)-S簇合物分子式导出可能结构的拓扑方法。作为例子，文中利用该方法导出了四核单Mo(W)簇合物的各种可能结构，并预测了簇合物［Mo2O2S6Cu4(PPh3)4］的各种可能结构。本文介绍的拓扑方法，为Mo(W)-Cu(Ag)-S簇合物的结构提供了一个组织框架，也为预测簇合物的新结构提供了一个合理的基础和途径。
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| 关 键 词： | 簇合物结构 连接矩阵 拓扑方法 |
TOPOLOGICAL RESEARCH OF THE Mo(W)-Cu(Ag)-S Cluster |
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| Jin Qionghu,Liu Jianming,Xin Xinquan and Tao Rongda.TOPOLOGICAL RESEARCH OF THE Mo(W)-Cu(Ag)-S Cluster[J].Chinese Journal of Inorganic Chemistry,1997,13(1):95-100. |
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| Authors: | Jin Qionghu Liu Jianming Xin Xinquan and Tao Rongda |
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| Institution: | Coordination Chemistry Institute, Nanjing University, Nanjing 210093;Department of Mathematics, Peking University, Beijing 100871,Coordination Chemistry Institute, Nanjing University, Nanjing 210093;Department of Mathematics, Peking University, Beijing 100871,Coordination Chemistry Institute, Nanjing University, Nanjing 210093;Department of Mathematics, Peking University, Beijing 100871 and Coordination Chemistry Institute, Nanjing University, Nanjing 210093;Department of Mathematics, Peking University, Beijing 100871 |
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| Abstract: | A topological method is outlined for deducing the possible structures from the given molecular formula of Mo(W) Cu(Ag) S clusters. As examples, the method is applied to deduce all possible structures of tetranuclear mono Mo(W) clusters and predict the structure of the cluster Mo 2O 2S 6(PPh 3) 4)]. The topological method introduced here provides an organizational framework for structures of Mo(W) Cu(Ag) S clusters, and offers an appropriate basis for predicting accessible new structures. |
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| Keywords: | structure of cluster connectivity matrix topological method |
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