Highly stable chiral (A)6-B supramolecular copolymers: a multivalency-based self-assembly process |
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| Authors: | Chen Shi-Gui Yu Yue Zhao Xin Ma Yuguo Jiang Xi-Kui Li Zhan-Ting |
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| Affiliation: | State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China. |
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| Abstract: | A novel type of chiral layered supramolecular copolymer with high molecular weight has been assembled from a hydrogen bonded C(6)-symmetric zinc porphyrin hexamer and chiral C(3)-symmetric pyridine hexadentate linkers driven by multivalent zinc porphyrin-pyridine coordination. UV-vis, circular dichroism, and static light scattering experiments revealed that the formation of the layered supramolecular copolymers is at first dynamically controlled and then becomes thermodynamically controlled. |
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