Panchromatic trichromophoric sensitizer for dye-sensitized solar cells using antenna effect |
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Authors: | Warnan Julien Buchet Fabien Pellegrin Yann Blart Errol Odobel Fabrice |
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Affiliation: | Laboratoire CEISAM, Equipe d'inge?nierie et de photonique mole?culaire UMR CNRS 6230 - Ba?t. 4 Faculte? des Sciences et des Techniques de Nantes BP 92208 2, rue de la Houssinie?re 44322 Nantes cedex 03, France. |
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Abstract: | The first trichromophoric sensitizer, consisting of covalently linked boradiazaindacene (BODIPY), zinc porphyrin (ZnP), and squaraine (SQ) units, has been synthesized by Heck alkynylation to obtain a panchromatic dye, for dye sensitized solar cells (DSSCs). Efficient intramolecular energy transfers (ET) were observed between all chromophoric subunits and enhance the overall conversion efficiency by 25%. The antenna effect is demonstrated by the photoaction spectrum which features all of a chromophore's absorption bands. |
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