Three-dimensional modeling of EXAFS spectral mixtures by combining Monte Carlo simulations and target transformation factor analysis |
| |
Authors: | Email author" target="_blank">Andre?RossbergEmail author Andreas?C?Scheinost |
| |
Institution: | (1) Biogeochemistry Group, Institute of Radiochemistry, Forschungszentrum Rossendorf e.V., 01314 Dresden, Germany;(2) The Rossendorf Beamline, ESRF, BP 220, 38043 Grenoble, France |
| |
Abstract: | We have developed a new method for the three-dimensional modeling of extended X-ray absorption fine structure (EXAFS) spectra
which enables the extraction of the local structure of aqueous metal complexes from spectral mixtures of several components.
The new method combines two techniques: Monte Carlo simulation and target transformation factor analysis (TFA). Monte Carlo
simulation is used to create random arrangements between the X-ray absorbing metal ion and the ligand atoms, and to calculate
the theoretical EXAFS spectrum of each arrangement. The theoretical EXAFS spectrum is then introduced as test spectrum in
the TFA procedure, to test whether or not the test spectrum is likely to be a component of the spectral mixtures. This coupled
procedure is repeated until the error in the test spectrum is minimized. The new method can thus be used to isolate and refine
the structure of complexes from spectral mixtures and to determine their relative concentrations, solely on the basis of an
estimate of a ligand structure. The performance of the proposed method is validated using uranium Liii-edge EXAFS spectra
of binary mixtures of two uranium(VI) 3,4-dihydroxybenzoic acid complexes. |
| |
Keywords: | EXAFS Complexation Speciation Factor analysis Monte Carlo Multiple scattering |
本文献已被 PubMed SpringerLink 等数据库收录! |
|