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First total synthesis of (−)-8-epi-9-deoxygoniopypyrone |
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| Authors: | Jean-Philippe Surivet Jean-Michel Vatèle |
| Institution: | Laboratoire de Chimie Organique 1, associé au CNRS, Université Claude Bernard CPE-Lyon, 43 Bd. du 11 Novembre 1918, 69622, Villeurbanne, France |
| Abstract: | The structure and absolute configuration of natural 8-epi-9-deoxygoniopypyrone have been confirmed by an efficient and highly diastereoselective synthesis in 15 steps from (S)-mandelic acid with an overall yield of 43%. |
| Keywords: | bicyclic heterocyclic compounds cleavage reaction hydroxylation styryllactones |
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