| An Unexpected Discovery in the Willgerodt-Kindler Reaction of Acetophenone——the Formation of the 4-（Benzoylthiocarbonyl）morpholine |
| |
| 引用本文： | 刘玮炜,赵跃强,许瑞波,唐丽娟,胡宏纹.An Unexpected Discovery in the Willgerodt-Kindler Reaction of Acetophenone——the Formation of the 4-（Benzoylthiocarbonyl）morpholine[J].中国化学,2006,24(10):1472-1475. |
| |
| 作者姓名： | 刘玮炜 赵跃强 许瑞波 唐丽娟 胡宏纹 |
| |
| 作者单位： | Department of Chemical Engineering Huaihai Institute of Technology，Lianyungang，Jiangsu 222005，China Department of Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemical Engineering，Huaihai Institute of Technology，Lianyungang，Jiangsu 222005，China，Department of Chemical Engineering，Huaihai Institute of Technology，Lianyungang，Jiangsu 222005，China，Department of Chemical Engineering，Huaihai Institute of Technology，Lianyungang，Jiangsu 222005，China，Department of Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China |
| |
| 基金项目： | Project supported by the National Natural Science Foundation of China(No.20072016)，Natural Science Foundation of Jiangsu Education Department(No.03KJB150009)，the Subject Foundation of Huaihai Institute of Technology(No.XK01009). |
| |
| 摘 要： | The Willgerodt-Kindler reaction of acetophenone was studied.Apart from the normal product 4-(benzylthio-carbonyl)morpholine,another product 4-(benzoylthiocarbonyl)morpholine was obtained unexpectedly.The struc-ture of the latter was confirmed by IR,~1H NMR spectra and X-ray diffraction analysis.The mechanism of the reac-tion was discussed.
|
| 关 键 词： | 4-（苯甲基硫代羰基）吗啉 4-（苯甲酰硫代羰基）吗啉 苯乙酮 Willgerodt-Kindler反应 晶体结构 |
| 收稿时间： | 2006-02-14 |
| 修稿时间： | 2006-02-142006-06-07 |
An Unexpected Discovery in the Willgerodt‐Kindler Reaction of Acetophenone––the Formation of the 4‐(Benzoylthio‐carbonyl)morpholine |
| |
| LIU Wei-Wei, ZHAO Yue-Qiang, XU Rui-Bo, TANG Li-Juan, HU Hong-Wen.An Unexpected Discovery in the Willgerodt‐Kindler Reaction of Acetophenone––the Formation of the 4‐(Benzoylthio‐carbonyl)morpholine[J].Chinese Journal of Chemistry,2006,24(10):1472-1475. |
| |
| Authors: | LIU Wei-Wei ZHAO Yue-Qiang XU Rui-Bo TANG Li-Juan HU Hong-Wen |
| |
| Institution: | 1. Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005, China; 2. Department of Chemistry, Nanjing University, Nanjing, Jiangsu 210093, China |
| |
| Abstract: | The Willgerodt-Kindler reaction of acetophenone was studied.Apart from the normal product 4-(benzylthio- carbonyl)morpholine,another product 4-(benzoylthiocarbonyl)morpholine was obtained unexpectedly.The struc- ture of the latter was confirmed by IR,~1H NMR spectra and X-ray diffraction analysis.The mechanism of the reac- tion was discussed. |
| |
| Keywords: | 4-(benzylthiocarbonyl)morpholine 4-(benzoylthiocarbonyl)morpholine acetophenone Willgerodt-Kindler reaction crystal structure |
| 本文献已被 CNKI 维普 等数据库收录！ |
